系统探讨了汉水水系水相(原水、滤水、悬浮物)、沉积物相中8个稀土元素的含量水平、丰度模式、悬浮物含量对水中元素含量的影响及沉积物粒度对元素的富集与分散作用等。结果表明:Eu、Lu主要以溶解态存在于水相中,而Sm主要存在于悬浮物中;汉水水中稀土元素的含量基本在世界淡水的范围内;湖库悬浮物中稀土元素含量均低于江河悬浮物,悬浮物和细粒沉积物中稀土元素含量相近,序列也基本一致;粒度对汉水沉积物中稀土元素含量的影响不明显;地表径流对水中悬浮物含量和悬浮物中稀土元素含量均有一定影响;稀土元素在汉水悬浮物、沉积物中均有一定程度的富集现象;汉水各相中均以轻稀土为主,重稀土含量较少。
This paper discusses systematically distribution characteristics,content levels,abundance modes, influence of suspended solid on element contents, effect of sediment granularity on enrichment and dispersion of eight rare earth elements in water phase (original water, filtrated water, suspended solid) and sediment phase in the Hanshui River.The results show the following laws. Eu,Lu are dissolved mainly in water column, and Sm is contained mostly in suspended solid;basically, contents of rare earth elements in the Hanshui River are within the range of average that of global fresh water;because of similarity of source and granularity of suspended solid and fine sediment, contents and abundance orders of rare earth elements in them are consistent basically; surface runofff affects on the content of suspended solid and rare earth elements in water. In all kinds of phases, the content of light rare earth elements(LREE) is higher than that of heavy rare earth elements(HREE).
[1] 陈莹,王晓蓉,彭安.稀土元素分馏作用研究进展[J].环境科学进展,1999,7(1):10~15.
[2] Paul Henderson(田丰,施琅译).稀土元素地球化学[M].北京:地质出版社,1989.4.
[3] 陈静生,洪松,王立新,等.中国东部河流颗粒物的地球化学性质[J].地理学报,2000,55(4):417~427.
[4] 王琦,于志刚,吴莹,等.罗纳河中悬浮物质的痕量元素的研究[J].海洋与湖沼,1998,29(2):197~204.
[5] Qu C H & Yan R E.Chemical composition and factors controlling suspended matter in three major Chinese rivers[J]. Sci. Total Environ.,1998:335-346.
[6] Zhu W. Distribution & modelling of rare earth elements in Chinese river sidements[J]. Sci. Total Environ.,1997, 204(3):233-243.
[7] 佘中盛.长江中下游典型水域水体环境背景值研究[M].北京:北京科学技术出版社,1992.9-14,122~124.
[8] 闫百兴,何岩.汉水沉积物中元素的地球化学特征[J].地理科学,1996,16(4):312~316.
[9] 赵振华.微量元素地球化学原理[M].北京:科学出版社,1997.224~225.
[10] 张立城,佘中盛,章申.水环境化学元素研究[M].北京:中国环境科学出版社,1996.276~284.
[11] 何岩,佘中盛,闫百兴.安徽太平湖水体环境中元素的地球化学特征[J].地理科学,1994,14(2):157~164.
[12] 中国环境监测总站.中国土壤元素背景值[M].北京:中国环境科学出版社,1990.152~219.